2015

“Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenases Strong C-H Bonds with Stereoretention
Joan Serrano-Plana, Williamson N. Oloo, Laura Acosta-Rueda, Katlyn K. Meier, Begoña Verdejo, Enrique García-España, Manuel G. Basallote, Eckard Münck, Lawrence Que Jr., Anna Company*, Miquel Costas
J. Am. Chem. Soc. 2015, 137, 15833-15842. DOI: 10.1021/jacs.5b09904

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“Design, Preparation, and Characterization of Zn and Cu Metallopeptides Based On Tetradentate Aminopyridine Ligands Showing Enhanced DNA Cleavage Activity
Marta Soler, Eduard Figueras, Joan Serrano-Plana, Marta González-Bartulos, Anna Masseguer, Anna Company, Ma Ángeles Martínez, Jaroslav Malina, Viktor Brabec, Lidia Feliu,* Marta Planas,* Xavi Ribas,* Miquel Costas*
Inorg. Chem. 2015, 54, 10542-10558. DOI: 10.1021/acs.inorgchem.5b01680

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“Activity Regioselective Access to Sultam Motifs through Cobalt-Catalyzed Annulation of Aryl Sulfonamides and Alkynes using an 8-Aminoquinoline Directing Group
Oriol Planas, Christopher J. Whiteoak,* Anna Company, Xavi Ribas*
Adv. Synth. Catal., 2015, 357, 4003-4012. DOI: 10.1002/adsc.201500690

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“C-H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight
Giorgio Olivo, Martina Nardi, Diego Vidal, Alessia Barberi, Andrea Lapi, Laura Gómez, Osvaldo Lanzalunga, Miquel Costas,* Stefano Di Stefano*
Inorg. Chem. 2015, 54, 10141-10152. DOI: 10.1021/acs.inorgchem.5b01500

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“Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2-O Bond Forming Reactions
Jordi Serra, Christopher J. Whiteoak, Ferran Acuña-Parés, Marc Font, Josep M. Luis, Julio Lloret-Fillol, Xavi Ribas*
J. Am. Chem. Soc. 2015, 137, 13389-13397. DOI: 10.1021/jacs.5b08756

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“Reactivity of a Nickel(II) Bis(Amidate) Complex meta-Chloroperbenzoic acid: Formation of a Potent Oxidizing Species
Teresa Corona, Florian F. Pfaff, Ferran Acuña-Parés, Apparao Draksharapu, Christopher J. Whiteoak, Vlad Martin-Diaconescu, Julio Lloret-Fillol, Wesley R. Browne, Kallol Ray, Anna Company*
Chem. Eur. J. 2015, 21, 15029-15038. DOI: 10.1002/chem.201501841

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“Nonheme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and Their Hydrogen-Atom and Oxygen-Atom Transfer Reaction
Mainak Mitra, Hassan Nimir, Serhiy Demeshko, Satish S. Bhat, Sergey O. Malinkin, Matti Haukka, Julio Lloret-Fillol, George C. Lisensky, Franc Meyer, Albert A. Shteinman, Wesley R. Browne, David A. Hrovat, Michael G. Richmond, Miquel Costas, Ebbe Nordlander*
Inorg. Chem. 2015, 54, 7152-7164. DOI: 10.1021/ic5029564

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“Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities
Joan Serrano-Plana, Isaac Garcia-Bosch, Anna Company,* Miquel Costas*
Acc. Chem. Res. 201548, 2397-2406. DOI: 10.1021/acs.accounts.5b00187

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“Computacional Insight into the Mechanism of Alkane Hydroxilation by Non-heme Fe(PyTACN) Iron Complexes. Effects of the Substrate and Solvent
Verònica Postils, Anna Company, Miquel Solà,* Miquel Costas, * Josep M. Luis*
Inorg. Chem. 201554, 8223-8236. DOI: 10.1021/acs.inorgchem.5b00583

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“Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives
Olaf Cussó, Xavi Ribas, Miquel Costas*
Chem. Commun. 201551, 14285-14298. DOI: 10.1039/C5CC05576H

Graphical abstract: Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

 

“H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2
Azin Hassanpour, Ferran Acuña-Parés, Josep M. Luis, Olaf Cussó, Silvia Morales de la Rosa, José Miguel Campos-Martín, Jose L. G. Fierro, Miquel Costas,* Julio Lloret-Fillol,* Rubén Mas-Ballesté*
Chem. Commun. 2015, 51, 14992-14995. DOI: 10.1039/C5CC06402C

Graphical abstract: H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2

 

“Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates”
Apparao Draksharapu, Davide Angelone, Matthew G. Quesne, Sandeep K. Padamati, Laura Gomez, Ronald Hage, Miquel Costas, Wesley R. Browne,* Sam P. de Visser*
Angew. Chem. Int. Ed. 201554, 4357-4361. DOI: 10.1002/anie.201411995

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“Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage”
Cristina Garcia-Simon, Rafael Gramage-Doria, Saeed Raoufmoghaddam, Teodor Parella, Miquel Costas,* Xavi Ribas,* Joost N. H. Reek*
J. Am. Chem. Soc. 2015137,  2680-2687. DOI: 10.1021/ja512637k

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“Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Coligands in H2O2 Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes”
Olaf Cussó, Xavi Ribas, Julio Lloret, Miquel Costas*
Angew. Chem. Int. Ed. 201554, 2729-2733. DOI: 10.1002/anie.201410557

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“Enzyme-triggered delivery of chlorambucil from conjugates based on the cell-penetrating peptide BP16”
Marta Soler, Marta González-Bártulos, Eduard Figueras, Xavi Ribas, Miquel Costas, Anna Massaguer, Marta Planas,* Lídia Feliu*
Org. Biomol. Chem. 2015, 13, 1470-1480. DOI: 10.1039/C4OB01875C

Graphical abstract: Enzyme-triggered delivery of chlorambucil from conjugates based on the cell-penetrating peptide BP16

 

“Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation”
Zoel Codolà, Laura Gómez, Scott T. Kleespies, Lawrence Que Jr., Miquel Costas, Julio Lloret-Fillol
Nature Commun. 20156, 5865. DOI: 10.1038/ncomms6865

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