2017

“Supramolecular recognition allows remote, site-selective C-H oxidation of methylenic sites in linear amines”
Giorgio Olivo*, Giulio Farinelli, Alessia Barbieri, Osvaldo Lanzalunga, Stefano Di Stefano*, Miquel Costas*
Angew. Chem. Int. Ed., 2017, Article ASAP. DOI: 10.1002/anie.201709280

“Carboxylate-Assisted Formation of Aryl-Co(III) Masked-Carbenes in Cobalt-Catalyzed C–H Functionalization with Diazo Esters”
Oriol Planas, Steven Roldán-Gómez, Vlad Martin-Diaconescu , Teodor Parella , Josep M. Luis, Anna Company, Xavi Ribas*
J. Am. Chem. Soc., 2017, Article ASAP. DOI: 10.1021/jacs.7b07880

“Mechanistically Driven Development of an Iron Catalyst for Selective Syn-Dihydroxylation of Alkenes with Aqueous Hydrogen Peroxide”
Margarida Borrell, Miquel Costas*
J. Am. Chem. Soc., 2017, 139 (36), 12821-12829. DOI: 10.1021/jacs.7b07909

“Tuning Selectivity in Aliphatic C–H Bond Oxidation of N-Alkylamides and Phthalimides Catalyzed by Manganese Complexes”
Michela Milan, Giulia Carboni, Michela Salamone, Miquel Costas*, Massimo Bietti*
ACS Catal., 2017, 7 (9), 5903-5911. DOI: 10.1021/acscatal.7b02151

“Evidence of a Sole Oxygen Atom Transfer Agent in Asymmetric Epoxidations with Fe-pdp Catalysts”
Olaf Cussó, Joan Serrano-Plana, Miquel Costas*
ACS Catal., 2017, 7, 5046-5053. DOI: 10.1021/acscatal.7b01184

“Nonclassical Single-State Reactivity of an Oxo-Iron(IV) Complex Confined to Triplet Pathways”
Claudia Kupper, Bhaskar Mondal, Joan Serrano-Plana, Iris Klawitter, Frank Neese, Miquel Costas, Shengfa Ye*, Franc Meyer*
J. Am. Chem. Soc., 2017, 139, 8939-8949. DOI: 10.1021/jacs.7b03255

“Generation, Spectroscopic, and Chemical Characterization of an Octahedral Iron(V)-Nitrido Species with a Neutral Ligand Platform”
Gerard Sabenya, Laura Lázaro, Ilaria Gamba, Vlad Martin-Diaconescu*, Erik Andris, Thomas Weyhermüller, Frank Neese*, Jana Roithova*, Eckhard Bill*, Julio Lloret-Fillol*, and Miquel Costas*
J. Am. Chem. Soc., 2017139, 9168-9177. DOI: 10.1021/jacs.7b00429

“Direct use of CO2 for O-arylcarbamate synthesis via mild Cu(II)-catalyzed aerobic C-H functionalization in pincer-like macrocyclic systems”
Elise Bernoud, Anna Company*, Xavi Ribas*
J. Organomet. Chem., 2017845, 44-48. DOI: 10.1016/j.organchem.2017.02.004

“CuI/CuIII prototypical organometallic mechanism for the deactivation of an active pincer-like CuI catalyst in Ullmann-type couplings”
Mireia Rovira, Lucie Jašíková, Erik Andris, Ferran Acuña-Parés, Marta Soler, Imma Güell, Ming-Zheng Wang, Laura Gómez, Josep M. Luis, Jana Roithová*, Xavi Ribas*
Chem. Comm, 2017. DOI: 10.1039/x0xx00000x

“Trifluoromethylation of a well-defined square planar aryl-Ni(II) complex involving Ni(III)/CF3· and Ni(IV)-CF3 intermediate species”
Mireia Rovira, Steven Roldán-Gómez, Vlad Martin-Diaconescu, Christopher J. Whiteoak, Anna Company, Josep M. Luis*, Xavi Ribas*
Chem. Eur. J., 2017. DOI: 10.1002/chem.201702168

“A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides”
Olaf Cussó, Michael W. Giuliano, Xavi Ribas, Scott J. Miller*, Miquel Costas*
Chem. Sci., 2017, 8, 3660-3667. DOI: 10.1039/C7SC00099E

“Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations”
Giorgio Olivo, Olaf Cussó, Margarida Borrell, Miquel Costas*
Biol. Inorg. Chem., 2017, 22, 425-452. DOI: 10.1007/s00775-016-1434-z

“Reversible C60 Ejection from a Metallocage through the Redox-Dependent Binding of a Competitive Guest”
Cédric Colomban, György Szalóki, Magali Allain, Laura Gómez, Sébastien Goeb*, Marc Sallé*, Miquel Costas*, Xavi Ribas*
Chem. Eur. J., 2017, 23, 3016–3022. DOI: 10.1002/chem.201700273

“A Copper-based Supramolecular Nanocapsule that Enables Straightforward Purification of Sc3N-based Endohedral Metallofullerene Soots”
Carles Fuertes-Espinosa, Cristina García-Simón, Edison Castro, Miquel Costas*, Luis Echegoyen*, Xavi Ribas*
Chem. Eur. J., 2017, 23, 3553–3557. DOI: 10.1002 /chem .201700046

“Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes”
Michela Milan, Massimo Bietti*, Miquel Costas*
ACS Cent. Sci., 2017, 3 (3), 196-204. DOI: 10.1021/acscentsci.6b00368

“Ligand and solvent effects in the formation and self-assembly of a metallosupramolecular cage”
N. N. Adarsh*, Amarnath Chakraborty*, Màrius Tarrés, Surjendu Dey, Fernando Novio, Basab Chattopadhyay, Xavi Ribas, Daniel Ruiz-Molina*
New J. Chem., 2017, 41, 1179–1185. DOI: 10.1039/C6NJ03456J

“Chasing the Evasive Fe=O Stretch and the Spin State of the Iron(IV)-Oxo Complexes by Photodissociation Spectroscopy”
Erik Andris, Rafael Navrátil, Juraj Jasik, Terencio Thibault, Martin Srnec*, Miquel Costas*, Jana Roithova*
J. Am. Chem. Soc., 2017, 139 (7), 2757-2765. DOI: 10.1021/jacs.6b12291

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“Activation of Dioxygen at a Lewis Acidic Nickel(II) Complex: Characterization of a Metastable Organoperoxide Complex”
Patrick Holze, Teresa Corona, Nicolas Frank, Beatrice Braun-Cula, Christian Herwig, Anna Company, Christian Limberg*
Angew. Chem. Int. Ed., 2017, 56, 2307-2311. DOI: 10.1002/anie.201609526

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“Au(III)-aryl intermediates in oxidant-free C–N and C–O cross-coupling catalysis”
Jordi Serra, Teodor Parella, Xavi Ribas*
Chem. Sci., 2017, 8, 946. DOI: 10.1039/C6SC03699F

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